IPC分类号：
B44F1/02 | B44F1/00 | B44C1/17 | D06Q1/12 | D06Q1/00 | D06Q1/10 | G02B5/12 | G02B5/128 | B44C1/165 | B32B31/00 | B32B3/00 | B32B5/16
当前申请(专利权)人：
MINNESOTA MINING AND MANUFACTURING COMPANY
原始申请(专利权)人：
MINNESOTA MINING AND MANUFACTURING COMPANY
当前申请(专利权)人地址：
St. Paul, MN
摘要：
A transfer sheet material for forming retroreflective graphic images on a substrate, the sheet material comprising a monolayer of transparent microspheres; a color layer printed over the microspheres in a first graphic segment of the sheet material in an imagewise pattern, the color layer comprising a transparent colorant in a transparent resin; a reflective layer printed over the microspheres in a second graphic segment of the sheet material in an imagewise pattern, the reflective layer comprising reflective flakes in a transparent binder, wherein the microspheres are partially embedded in at least one of the color layer and the reflective layer, individual microspheres having the reflective flakes arranged in cup-like fashion about their embedded portions; and a bonding layer printed over the color layer and the reflective layer, the bonding layer being sufficiently thick to embed all exposed surfaces of the color layer and the reflective layer and being adapted for use in securing the sheet material to a substrate. Also, a method for making such a sheet material.
技术问题语段：
Insofar as known, no one has previously found a practical or commercially useful way to provide such retroreflective emblems.|Some have proposed silk-screening a design onto a garment, and then while the design is still wet, cascading microspheres onto the design; but such an approach is messy, usually provides a nonuniform deposit of microspheres, and is impractical for obtaining high reflective brightness (which requires that the embedded surfaces of the microspheres be covered with a specularly reflective layer).|Still others long ago proposed the preparation of retroreflective decals comprising a layer of glass microspheres disposed over a printed design (see U.S. Pat. No. 2,422,256 (Phillippi)); but the suggested decal was a several-layer product which was likely stiff and unsuited for conformable garments.|But none of these commercial products is useful to form the complex multi-colored designs that are in fashion and are needed to maximize the use of retroreflective emblems.|The result is that, in spite of the above-described efforts, multi-colored designs or emblems on garments continue to be made non-retroreflective and the potential use of such emblems for safety purposes goes unrealized.
技术功效语段：
Sheet materials of the invention can be used to provide substrates with graphic images comprising non-reflecting colored areas and retroreflective areas, with at least some of the retroreflective areas typically being capable of brilliantly retroreflecting the color of the image provided in these areas. Fabric substrates comprising such transferred graphic images can exhibit good wash durability (i.e., launderability) and can also exhibit good drycleaning durability.
权利要求：
What is claimed is:
1. A method of making a transfer sheet material that is adapted to be used in transferring retroreflective graphic images from the sheet material to a substrate, comprising:
a) providing a carrier comprising a base sheet and a heat-softenable layer on the base sheet;
b) cascading a monolayer of transparent microspheres onto the heat-softenable layer and embedding the microspheres in the heat-softenable layer to a depth averaging between about 25 and about 50 percent of their diameters;
c) printing onto the microspheres in a first graphic segment of the sheet material in a first imagewise pattern with a colorant composition comprising a transparent colorant in a transparent resin and drying the colorant composition to form a color layer;
d) thereafter printing onto the microspheres in a second graphic segment of the sheet material in a second imagewise pattern with a reflective layer composition comprising reflective flakes in a transparent binder and drying the reflective layer composition to form a reflective layer, wherein the microspheres are partially embedded in at least one of the color layer and the reflective layer, individual microspheres having the reflective flakes arranged in a cup-shaped fashion about their embedded portions; and
e) thereafter printing onto the first and second graphic segments of the sheet material with a bonding composition to a depth sufficient to embed all exposed surfaces of the color layer and the reflective layer and drying the bonding composition to form a bonding layer.
2. The method of claim 1 further comprising printing in the first graphic segment of the sheet material with a second colorant composition comprising a second transparent colorant in a second transparent resin and drying the second colorant composition to form a second color layer.
3. The method of claim 1 wherein the reflective flakes are selected from the group consisting of metal flakes and nacreous pigment particles.
4. The method of claim 1 wherein the reflective flakes have ellipsoidal shapes.
5. The method of claim 1 wherein the reflective flakes have a thickness in the range of about 0.03 to about 0.8 microns.
6. The method of claim 1 wherein the microspheres are embedded in the heat-softenable layer to a depth averaging between about 40 and about 50 percent of their diameters.
7. The method of claim 1 wherein the colorant composition, the reflective layer composition, and the bonding composition are printed by use of a screen printing process.
8. The method of claim 1 wherein the transparent colorant comprises a transparent pigment.
9. The method of claim 1 wherein the transparent resin comprises polyurethane and the transparent binder comprises polyester.
10. The method of claim 1 therein the colorant composition and the reflective layer composition are printed in such a manner that they at least partially overlap with the color layer disposed between the microspheres and the reflective layer to provide a segment of the sheet material which is adapted to retroreflect the color of the color layer when the microspheres in this segment are illuminated with a beam of incident light.
11. The method of claim 1 wherein the bonding composition is printed to a wet thickness of about 50 to about 100 microns.
12. The method of claim 1 wherein the bonding layer is formed by printing onto the first and second graphic segments of the sheet material with an extender resin and fusing an elastomeric, heat-activatable, hot-melt adhesive powder into the extender resin.
13. The method of claim 12 wherein the extender resin comprises polyester.
14. The method of claim 12 wherein the hot-melt adhesive powder comprises an elastomer selected from the group consisting of polyesters and polyamides.
15. The method of claim 1, wherein the resulting bonding layer is adapted for use in subsequently adhesively bonding the transfer sheet material to a substrate.