IPC分类号：
B44F1/02 | B44C1/17 | B44F1/00 | D06Q1/12 | D06Q1/10 | D06Q1/00 | G02B5/12 | G02B5/128 | B32B5/16
当前申请(专利权)人：
MINNESOTA MINING AND MANUFACTURING COMPANY
原始申请(专利权)人：
MINNESOTA MINING AND MANUFACTURING COMPANY
当前申请(专利权)人地址：
P.O. BOX 33427, 55133-3427, ST. PAUL, MINNESOTA
代理机构：
GRISWOLD, GARY L. KIRN, WALTER N. KNAUER, RICHARD T.
摘要：
A transfer sheet material for forming retroreflective graphic images on a substrate, the sheet material comprising a monolayer of transparent microspheres; a color layer printed over the microspheres in a first graphic segment of the sheet material in an imagewise pattern, the color layer comprising a transparent colorant in a transparent resin; a reflective layer printed over the microspheres in a second graphic segment of the sheet material in an imagewise pattern, the reflective layer comprising reflective flakes in a transparent binder, wherein the microspheres are partially embedded in at least one of the color layer and the reflective layer, individual microspheres having the reflective flakes arranged in cup-like fashion about their embedded portions; and a bonding layer printed over the color layer and the reflective layer, the bonding layer being sufficiently thick to embed all exposed surfaces of the color layer and the reflective layer and being adapted for use in securing the sheet material to a substrate. Also, a method for making such a sheet material.
技术问题语段：
Insofar as known, no one has previously found a practical or commercially useful way to provide such retroreflective emblems.|Some have proposed silk-screening a design onto a garment, and then while the design is still wet, cascading microspheres onto the design; but such an approach is messy, usually provides a nonuniform deposit of microspheres, and is impractical for obtaining high reflective brightness (which requires that the embedded surfaces of the microspheres be covered with a specularly reflective layer).|Still others long ago proposed the preparation of retroreflective decals comprising a layer of glass microspheres disposed over a printed design (see U.S. Pat. No. 2,422,256 (Phillippi)); but the suggested decal was a several-layer product which was likely stiff and unsuited for conformable garments.|But none of these commercial products is useful to form the complex multi-colored designs that are in fashion and are needed to maximize the use of retroreflective emblems.|The result is that, in spite of the above-described efforts, multi-colored designs or emblems on garments continue to be made non-retroreflective and the potential use of such emblems for safety purposes goes unrealized.
技术功效语段：
Sheet materials of the invention can be used to provide substrates with graphic images comprising non-reflecting colored areas and retroreflective areas, with at least some of the retroreflective areas typically being capable of brilliantly retroreflecting the color of the image provided in these areas. Fabric substrates comprising such transferred graphic images can exhibit good wash durability (i.e., launderability) and can also exhibit good drycleaning durability.
权利要求：
What is claimed is:
1. A transfer sheet material for forming retroreflective graphic images on a substrate, the sheet material comprising:
a) a monolayer of transparent microspheres;
b) a color layer printed over the microspheres in a first graphic segment of the sheet material in an imagewise pattern, the color layer comprising a transparent colorant in a transparent resin;
c) a reflective layer printed over the microspheres in a second graphic segment of the sheet material in an imagewise pattern in such a manner that any overlapping areas of the first and second graphic segments are characterized by the color layer being disposed between the microspheres and the reflective layer, the reflective layer comprising reflective flakes in a transparent binder, wherein the microspheres are partially embedded in at least one of the color layer and the reflective layer, the reflective flakes being small enough relative to the microspheres that individual microspheres have the reflective flakes arranged in cup-like fashion about their embedded portions; and
d) a bonding layer printed over the color layer and the reflective layer, the bonding layer being sufficiently thick to embed all exposed surfaces of the color layer and the reflective layer and being adapted for use in securing the sheet material to a substrate.
2. The sheet material of claim 1 further comprising a second color layer printed in the first graphic segment in an imagewise pattern, the second color layer comprising a second transparent colorant in a second transparent resin.
3. The sheet material of claim 1 bonded to a substrate through the bonding layer.
4. The sheet material of claim 3 wherein the substrate is a fabric.
5. The sheet material of claim 1 wherein the reflective flakes are selected from the group consisting of metal flakes and nacreous pigment particles.
6. The sheet material of claim 1 wherein the reflective flakes have ellipsoidal shapes.
7. The sheet material of claim 1 wherein the reflective flakes have a thickness in the range of about 0.03 to about 0.8 microns.
8. The sheet material of claim 1 further comprising a carrier comprising a base sheet and a heat-softenable layer on the base sheet, the microspheres being embedded in the heat-softenable layer to a depth averaging between about 25 and about 50 percent of their diameters.
9. The sheet material of claim 8 wherein the microspheres are embedded in the heat-softenable layer to a depth averaging between about 40 and about 50 percent of their diameters.
10. The sheet material of claim 1 wherein the transparent colorant comprises a transparent pigment.
11. The sheet material of claim 1 wherein the transparent resin comprises polyurethane and the transparent binder comprises polyester.
12. The sheet material of claim 1 wherein the color layer and the reflective layer at least partially overlap with the color layer disposed between the microspheres and the reflective layer to provide a segment of the sheet material which is capable of retroreflecting the color of the color layer when the microspheres in this segment are illuminated with a beam of incident light.
13. The sheet material of claim 1 wherein the bonding layer comprises an extender resin and an elastomeric, heat-activatable, hot-melt adhesive powder fused into the extender resin.
14. The sheet material of claim 13 wherein the extender resin comprises polyester.
15. The sheet material of claim 13 wherein the hot-melt adhesive powder comprises an elastomer selected from the group consisting of polyesters and polyamides.