An alpha titanium alloy for additive manufacturing

公开(公告)号:
GB201815536D0
公开(公告)日:
2018-11-07
申请号:
GB2018015536
申请日:
2018-09-24
授权日:
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受理局:
英国
专利类型:
发明申请
简单法律状态:
失效
法律状态/事件:
撤回-未指定类型
IPC分类号:
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战略新兴产业分类:
先进有色金属材料
国民经济行业分类号:
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当前申请(专利权)人:
OXMET TECHNOLOGIES LIMITED
原始申请(专利权)人:
OXMET TECHNOLOGIES LIMITED
当前申请(专利权)人地址:
King Charles House, Park End Street, Oxford, Oxfordshire, OX1 1JD , United Kingdom
工商统一社会信用代码:
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工商登记状态:
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工商注册地址:
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工商成立日期:
2017-03-23
工商企业类型:
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发明人:
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代理机构:
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代理人:
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摘要:
A titanium-based alloy consisting in weight percent, of: 4.0-8.0 % aluminium, 3.0-9.0 % tin, 0-5.0 % zirconium, 0-2.0 % niobium, 0-2.0 % vanadium, 0-0.5 % iron, 0-1.75 % chromium, 0-2.0 % molybdenum, 0-0.5 % nickel, 0-0.5 % tantalum, 0-0.5 % cobalt, 0-0.75 % silicon, 0-0.5 % boron, 0-0.5 % calcium, 0-0.5 % carbon, 0-0.5 % manganese and 0-0.5 hafnium, with the balance being titanium and incidental impurities and where 0.107Al + 0.075V + 0.4Fe + 0.112Cr + 0.025Zr + 0.05Mo + 0.082Nb + 0.027Sn > 1.0. The alloy can be used to make powder which can be used in additive layer manufacturing and comprises at least 90 % of alpha phase.
技术问题语段:
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技术功效语段:
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权利要求:
Claims 1. Atitanium-based alloy composition consisting in weight percent, of. between 4.0 and 8.0 % aluminium, between 3.0 and 9.0% tin, between 0.0 and 5.0% zirconium, between 0.0 and 2.0% niobium, between 0.0 and 2.0% vanadium, between 0.0 and 0.5% iron, between 0.0 and 1.75% chromium, between 0.0 and 2.0% molybdenum, between 0.0 and 0.5 % nickel, between 0.0 and 0.5 % tantalum, between 0.0 and 0.5% cobalt, between 0.0 and 0.75% silicon, between 0.0 and 0.5% boron, between 0.0 and 0.5% calcium, between 0.0 and 0.5% carbon, between 0.0 and 0.5% manganese, between 0.0 and .0.5 hafnium, the balance being titanium and incidental impurities which satisfies the following relationship: 0.107Al + 0.075V + 0.4Fe + 0.112Cr + 0.025Zr + 0.05Mo + 0.082Nb + 0.027Sn > 10 where Al, V, Fe, Cr, Zr, Mo, Nb and Sn represent the amounts of aluminium, vanadium, iron, chromium, zirconium, molybdenum, niobium and tin in wt.% respectively. 2. The titanium-based alloy composition of claim 1, consisting of 1.75% or less molybdenum, preferably 1.5% or less, more preferably 1.25% or less molybdenum, even more preferably 1.0% or less molybdenum. 3. The titanium-based alloy composition of claim 1 or 2, consisting of 0.5% or more molybdenum, preferably 0.6% or more molybdenum, more preferably 0.75% or more molybdenum. 4. The titanium-based alloy composition of claim 1, 2 or 3, which satisfies the following equation 7.0 < Alwt.% + zSnwt.% +3 Zr wt.% < 10.0 preferably 1 1 7.0 < Alwt.% + Sn wt. % +eZrwt % <9.0 where Al, Sn and Zr represent the amounts of aluminium, tin and zirconium in wt % respectively. 5. The titanium-based alloy composition of any of claims 1 to 4, consisting of 8.5% or less tin, preferably 8.0% or less tin, more preferably 7.5% or less tin. 6. The titanium-based alloy composition of any of claims 1 to 5, consisting of 5.5% or more tin, preferably 6.0% or more tin. 7. The titanium-based alloy composition of any of claims 1 to 6, consisting of 4.5% or less zirconium, preferably 4.0% or less zirconium, more preferably 3.5% or less zirconium. 8. The titanium-based alloy composition of any of claims 1 to 7, consisting of 1.0% or more zirconium, preferably 1.5% or more zirconium, more preferably 2.0% or more zirconium. 9. The titanium-based alloy composition of any of claims 1 to 8, consisting of 1.75% or less vanadium, preferably 1.5% or less vanadium, more preferably 1.25% or less vanadium, even more preferably 1.0% or less vanadium. 10. The titanium-based alloy composition of any of claims 1 to 9, consisting of 0.5% or more vanadium, preferably 0.75% or more vanadium, more preferably 1.0% or more vanadium. 11. The titanium-based alloy composition of any of claims 1 to 10, consisting of 0.25% or less iron, preferably 0.15% or less iron. 12. The titanium-based alloy composition of any of claims 1 to 11, consisting of 0.1% or more iron, preferably 0.2% or more iron. 13. The titanium-based alloy composition of any of claims 1 to 12, which satisfies the flowing equation 800<883—-150Fewt.% —96Crwt.% —49 Mo wt.% —37V wt. % —17Nbwt.% —12Tawt.% — 7 Zr wt.% — 3 Sn wt. % + 15 Al wt. % in which Fe, Cr, Mo, V, Nb, Ta, Zr, Sn and Al represent the amounts of iron, chromium, molybdenum, vanadium, niobium, tantalum, zirconium, tin and aluminium in wt% respectively. 14. The titanium-based alloy composition of any of claims 1 to 13, consisting of 75.0 wt% or more titanium, preferably 80.0 wt% or more titanium. 15. The titanium-based alloy composition of any of claims 1 to 14, consisting of 1.5% or less chromium, more preferably 1.0% or less chromium, more preferably 0.75% or less chromium. 16. The titanium-based alloy composition of any of claims 1 to 15, consisting of 0.15% or more chromium, preferably 0.25% or more chromium, more preferably 0.35% or more chromium. 17. The titanium-based alloy composition of any of claims 1 to 16, consisting of 1.5% or less niobium, more preferably 1.25% or less niobium. 18. The titanium-based alloy composition of any of claims 1 to 17, consisting of 0.25% or more niobium, preferably 0.5% or more niobium, more preferably 0.75% or more niobium, even more preferably 1.0% or more niobium. 19. The titanium-based alloy composition of any of claims 1 to 18, consisting of 0.25% or less boron. 20. The titanium-based alloy composition of any of claims 1 to 19, consisting of 0.05% or more boron. 21. The titanium-based alloy composition of any of claims 1 to 20 consisting of 0.5% or less silicon. 22. The titanium-based alloy composition of any of claims 1 to 22, consisting of 0.15% or more silicon, preferably 0.25% or more silicon. 23. The titanium-based alloy composition of any of claims 1 to 21, which satisfies the flowing equation 50Al + 35V + 75Fe + 65Cr + 20Zr + 50Mo + 15Nb + 258n 2 550, preferably2600 in which Fe, Cr, Mo, V, Nb, Ta, Zr, Sn and Al represent the amounts of iron, chromium, molybdenum, vanadium, niobium, tantalum, zirconium, tin and aluminium in wt% respectively. 24. The titanium-based alloy composition of any of claims 1 to 21, which satisfies the flowing equation 0.076A] + 0.0153V + 1.53Fe + 023Cr + 0.025Zr + 0.05Mo + 0.028Nb + 0.0538Sn>1.0 in which Fe, Cr, Mo, V, Nb, Ta, Zr, Sn and Al represent the amounts of iron, chromium, molybdenum, vanadium, niobium, tantalum, zirconium, tin and aluminium in wt% respectively. 25. The titanium-based alloy composition of any of claims 1 to 24, consisting of 0.1 wt% or more hafnium. 26. The titanium-based alloy composition of any of claims 1 to 25, wherein the sum of wt % of each of cobalt, nickel and manganese is 1.0 wt. % or less, preferably 0.5 wt% or less. 27. The titanium-based alloy composition of any of claims 1 to 26, consisting of 5.0 wt.% or more aluminium, preferably 6.0 wt.% or more aluminium. 28. The titanium-based alloy composition of any of claims 1 to 27 consisting of 7.5Wt.% or less aluminium preferably 7.0% or less aluminium. 29. The titanium-based alloy composition of any of claims 1 to 28, wherein the sum in weight percent of chromium, cobalt, iron, nickel and manganese is 1.75 wt.% or less, preferably of 1.5 wt.% or less, more preferably 1.0 wt.% or less, more preferably 0.75 wt.% or less. 30. The titanium-based alloy composition of any of claims 1 to 29, wherein the alloy has a microstructure of at least 90% alpha phase. 31. The titanium-based alloy composition of any of claims 1 to 30, which satisfies the flowing equation 0.107Al + 0.075V + 0 4Fe + 0.112Cr + 0.025Zr + 0.05Mo + 0.082Nb + 0.027Sn>1.05 where Al, V, Fe, Cr, Zr, Mo, Nb and Sn represent the amounts of aluminium, vanadium, iron, chromium, zirconium, molybdenum, niobium and tin in wt.% respectively. 32. The titanium-based alloy composition of any of claims 1 to 31, which satisfies the flowing equation 44370 27Al 785Fe 549V 10.18Mo 6.49Zr 7.85Cr 8.6Nb 7.315n 1665Ta 13.07Hf B89INi 7.3Mn 886Co 2378 2.5750 Los 7766 + 2608 * 5564 1 5004 1 9394 + 9122 ' 5199 10250 ' 11671 ' 18004 ' 17849 3869 ' 5493 ' 5893 ' 1081 ' 2808 ) Ti Al V Fe Mo Zr Cr Nb Sn Ta Hj Ni. Mn Co B Si prt ba EE MO 2 Cr NE Sh Te HL NE Mo BS preferably 44371 2.7Al 785Fe 5.49V 10.18Mo 6.49Zr 7.85Cr A 8.6Nb 7.315n 16.65Ta , 13.07Hf A BINi 7.3Mn 886Co 2.378 2.575 103 (475 +7698 * 5364 T3094 * T9394 +0122 T5199 +9200 T 11671 * 18094 © 17849 T3869 * 3493 * 5893 1081 * 2808 ) TC Ml, V Fe Mo, Zr , Cr Nb Sn _ Ta _ Hf . NL, Mn, CoB 5 Tec t3cos zoos tas T9593 T9133 T3195 T9300 T1171 T 18093 T T9635 T 2865 T 2393 T3593 T 1051 T 7508 < 4.62 wherein Ti, Al, V, Fe, Cr, Zr, Mo, Nb, Sn, Ta, Hf, Ni, Mn, Co, B and Si represent the amounts of titanium, aluminium, vanadium, iron, chromium, zirconium, molybdenum, niobium, tin, tantalum, hafnium, nickel, manganese, cobalt, boron and silicon in wt.% respectively. 33. An additive manufacturing component made of the titanium-based alloy of any of claims 1-32. 34. A method of additive manufacturing an article uses the titanium-based alloy of any of claims 1-32.
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