发明人:
ADAMI, GIOVANNI | AMIS, SAM | BIANCONI, MIRKO | CAVALIERE, SERGIO | CHEN, YUCHUNG K. | GREEN, JESSICA | HIPP, STEPHEN | HURD, JOHN | MCLACHLAN, OLIVER | MENENGHINI, NICOLAS | MOLYNEUX, JAMES | PINI, PIERANGELO | RUSBROOK, THOMAS J. | SMITH, TIMOTHY J. | WINCEK, CHRISTIANNA
摘要:
An article, comprising: a first reflowed material (712); and a second element (708) selected from a second shaped component, a second film, a second textile, a second yarn, or a second fiber. The first reflowed material (712) is a melted and re-solidified product of a first element selected from a first shaped component, a first film, a first yarn, a first fiber, a first textile, or any combination thereof. The second element is a dyed second element, whereas the first reflowed material is substantially free of the dye (716). Also related articles and methods.
权利要求:
1. An article (100; 102; 100a; 200; 202; 300; 1200; 1212; 1214; 1400; 1500), comprising: - a first reflowed material; and - a second element selected from a second shaped component, a second film, a second textile, a second yarn, or a second fiber; wherein the first reflowed material is a melted and re-solidified product of a first element selected from a first shaped component, a first film, a first yarn, a first fiber, a first textile, or any combination thereof; wherein the first reflowed material comprises a low processing temperature polymeric composition, the low processing temperature polymeric composition comprising one or more first thermoplastic polymers and exhibiting a melting temperature Tm that is from 80 °C to 135 °C; wherein the second element comprises a high processing temperature polymeric composition, the high processing temperature polymeric composition comprising one or more second thermoplastic polymers; and wherein the high processing temperature polymeric composition exhibits: 1) a creep relaxation temperature Tcr; 2) a heat deflection temperature Thd; and 3) a Vicat softening temperature Tvs that are each at least 10 °C greater than the melting temperature Tm of the low processing temperature polymeric composition; wherein, while at least a portion of the first element and at least a portion of the second element is on a molding surface (1520), the temperature of the entire article (100; 102; 100a; 200; 202; 300; 1200; 1212; 1214; 1400; 1500) has been increased to a temperature that is above the melting temperature Tm of the low processing temperature polymeric composition and below: 1) the creep relaxation temperature Tcr; 2) the heat deflection temperature Thd; and 3) the Vicat softening temperature Tvs of the high processing temperature polymeric composition; and wherein the second element is a dyed second element, wherein the high processing temperature polymeric composition of the second element comprises a dye, and the first reflowed material is substantially free of the dye.
2. The article (100; 102; 100a; 200; 202; 300; 1200; 1212; 1214; 1400; 1500) according to claim 1, wherein the first element is selected from a yarn or a fiber, wherein the first element is formed from a low processing temperature polymeric composition that is free of pigments or dyes, and wherein the region (104; 104a; 302; 1710) of the article comprising the low processing temperature polymeric composition is clear or transparent.
3. The article (100; 102; 100a; 200; 202; 300; 1200; 1212; 1214; 1400; 1500) according to claim 2, wherein the dyed second element is selected from a package dyed yarn or a package dyed fiber.
4. The article (100; 102; 100a; 200; 202; 300; 1200; 1212; 1214; 1400; 1500) according to claim 1, wherein the article (100; 102; 100a; 200; 202; 300; 1200; 1212; 1214; 1400; 1500) includes the first film, the first textile, the second shaped component, the second film, or the second textile, or combinations thereof, comprising a first printed marking on at least a portion thereof.
5. The article (100; 102; 100a; 200; 202; 300; 1200; 1212; 1214; 1400; 1500) according to claim 4, wherein the first printed marking is a screen printed marking.
6. The article (100; 102; 100a; 200; 202; 300; 1200; 1212; 1214; 1400; 1500) according to claim 1, wherein the article (100; 102; 100a; 200; 202; 300; 1200; 1212; 1214; 1400; 1500) includes the first film, the first textile, the second film, or the second textile, or combinations thereof, comprising embroidery on at least a portion thereon.
7. The article (100; 102; 100a; 200; 202; 300; 1200; 1212; 1214; 1400; 1500) according to claim 1, wherein the dyed second element is an anionic dyed second element.
8. The article (100; 102; 100a; 200; 202; 300; 1200; 1212; 1214; 1400; 1500) according to claim 1, wherein the article (100; 102; 100a; 200; 202; 300; 1200; 1212; 1214; 1400; 1500) includes a first reflowed material comprising a second printed marking on at least a portion thereof.
9. A process (2200, 2300, 2400) for manufacturing an article (100; 102; 100a; 200; 202; 300; 1200; 1212; 1214; 1400; 1500), the process comprising: - receiving (2210, 2310, 2410) a first element selected from a first shaped component, a first film, a first textile, a first yarn, and a first fiber; and/or - receiving (2210, 2310, 2410) a second element selected from a second shaped component, a second film, a second textile, a second yarn, or a second fiber; wherein the first element comprises a low processing temperature polymeric composition, the low processing temperature polymeric composition comprising one or more first thermoplastic polymers and exhibiting a melting temperature Tm that is from 80 °C to 135 °C, wherein the second element is a dyed second element comprising a high processing temperature polymeric composition, the high processing temperature polymeric composition comprising one or more second thermoplastic polymers, and wherein the high processing temperature polymeric composition exhibits: 1) a creep relaxation temperature Tcr; 2) a heat deflection temperature Thd; and 3) a Vicat softening temperature Tvs that are each at least 10 °C greater than the melting temperature Tm of the low processing temperature polymeric composition; - placing (2220, 2320, 2420) at least a portion of the first element and at least a portion of the second element on a molding surface (1520); - while the at least a portion of the first element and the at least a portion of the second element is on the molding surface (1520), increasing (2230, 2330, 2430) a temperature of the entire article (100; 102; 100a; 200; 202; 300; 1200; 1212; 1214; 1400; 1500) to a temperature that is above the melting temperature Tm of the low processing temperature polymeric composition and below: 1) the creep relaxation temperature Tcr; 2) the heat deflection temperature Thd; and 3) the Vicat softening temperature Tvs of the high processing temperature polymeric composition; and - subsequent to the increasing the temperature of the entire article (100; 102; 100a; 200; 202; 300; 1200; 1212; 1214; 1400; 1500), while the at least a portion of the article (100; 102; 100a; 200; 202; 300; 1200; 1212; 1214; 1400; 1500) remains on the molding surface, decreasing (2240, 2340, 2440) the temperature of the entire article (100; 102; 100a; 200; 202; 300; 1200; 1212; 1214; 1400; 1500) to a temperature below the melting temperature Tm of the low processing temperature polymeric composition; thereby forming an article (100; 102; 100a; 200; 202; 300; 1200; 1212; 1214; 1400; 1500) comprising a first reflowed material; wherein the first reflowed material is a melted and re-solidified product of the first element selected from the first shaped component, the first film, the first yarn, the first fiber, the first textile, or any combination thereof; wherein the first reflowed material comprises a low processing temperature polymeric composition, the low processing temperature polymeric composition comprising one or more first thermoplastic polymers, wherein the high processing temperature polymeric composition of the second element comprises a dye, and the first reflowed material is substantially free of the dye.
10. The process (2200, 2300) for manufacturing an article (100; 102; 100a; 200; 202; 300; 1200; 1212; 1214; 1400; 1500) according to claim 9, wherein the article (100; 102; 100a; 200; 202; 300; 1200; 1212; 1214; 1400; 1500) is an article (100; 102; 100a; 200; 202; 300; 1200; 1212; 1214; 1400; 1500) according to any one of claims 1 to 8.